The value of the element
lead in brass alloys lies in the fact that it has a low melting
point, 620ºF, and that it is virtually insoluble in solid copper,
(less than 50 parts per million). These reasons explain the longtime
use of lead in the creation of castings. For example, red brasses
are wide freezing range alloys, which means that as they solidify,
countless microscopic strutures called dendrites are formed. These
dendrites then tend to lock into one another, leaving voids known
as microporosity during solidification.
The role of lead in
a brass casting is to fill these microvoids and make the entire
casting pressure tight. Also, the distribution of lead into a copper
matrix adds to its machinability. A.R. Singh was determined to find
an applicable method to replace the lead in his castings with a
non-toxic element.
Bismuth, with a melting
point of 520ºF and located next to lead on the periodic table, exhibits
similar properties and was an excellent choice as a lead replacement.
The distinguishing factor between the two is that lead is soft and
malleable, whereas bismuth is hard and brittle. In his research,
Mr. Singh concluded that the introduction of a proprietary additive
in a unique manner helps distribute bismuth uniformly throughout
the alloy structure. This special feature virtually eliminates the
problems associated with the embrittlement of bismuth and is essential
for Federalloy alloys to exhibit excellent pressure tightness and
comparable mechanical properties as are in leaded brass castings.